Platinum Nanoclusters-Modified Porous In2O3 Nanocubes for Highly Sensitive and Selective Formaldehyde Gas Sensing at Room Temperature

甲醛 纳米团簇 选择性 材料科学 检出限 吸附 铂金 氧气 纳米技术 金属 多孔性 化学工程 氧化物 无机化学 催化作用 化学 物理化学 色谱法 有机化学 复合材料 冶金 工程类
作者
Liangyu Zhai,Gangqiang Zhu,Fei Rao,Zehan Liu,Weibin Zhang,Lujun Zhu,Xianjin Shi,Yu Huang,Yanmin Jia,Mirabbos Hojamberdiev
出处
期刊:Sensors and Actuators B-chemical [Elsevier BV]
卷期号:399: 134805-134805 被引量:17
标识
DOI:10.1016/j.snb.2023.134805
摘要

The detection of formaldehyde gas generally requires a relatively high temperature. It is still challenging to simultaneously possess high sensitivity and strong selectivity for the detection of low-concentration formaldehyde at room temperature. The activation energy of the reaction can be reduced by introducing oxygen vacancies or loading the metal clusters on the surface of metal oxide-based semiconductors, leading to an improvement in the performance and detection limit of the sensor. However, this approach may lead to an increased cross-sensitivity to other gases and a reduction in the selectivity of the sensors. In this study, In2O3 can capture a significant amount of adsorbed oxygen by increasing the oxygen vacancies and introducing platinum nanoclusters on the surface of In2O3 synthesized with a specific morphology, leading to high sensitivity and selectivity for the detection of formaldehyde gas at room temperature. The Pt-In2O3 sensor exhibits a response value of approximately 38 to 1 ppm formaldehyde at 20 oC. Moreover, the developed sensor demonstrates excellent performance in a complex atmosphere and exhibits good long-term stability. The achieved high sensitivity and selectivity for the detection of formaldehyde gas at low temperatures hold significant implications for research and practical applications in the field of sensors.
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