化学
共轭体系
胺气处理
亚苯基
电荷(物理)
组合化学
光化学
有机化学
聚合物
物理
量子力学
作者
Agnieszka Proń,Gang Zhou,Hassan Norouzi‐Arasi,Martin Baumgarten,Kläus Müllen
出处
期刊:Organic Letters
[American Chemical Society]
日期:2009-08-20
卷期号:11 (16): 3550-3553
被引量:29
摘要
Novel boron-nitrogen-containing pi-conjugated compounds 3,3'- and 4,4'-((2,4,6-triisopropylphenyl)borylene)bis(N,N-diarylbenzenamine) (1-2), m- and p-phenylene bridged to the boron center, respectively, have been synthesized and characterized. Optical studies by means of UV-vis absorption and emission measurements as well as DFT calculations reveal a different charge transfer behavior between the para series and the meta series at ground and excited states.
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