化学
甘氨酸
糖苷
催化作用
衍生工具(金融)
有机化学
组合化学
立体选择性
经济
金融经济学
作者
Nan Jiang,Zhengliang Wu,Youxian Dong,Xiaoxia Xu,Xiaxia Liu,Jianbo Zhang
标识
DOI:10.2174/1385272824666200130111142
摘要
The substitution reaction of glycal (1,2-unsaturated cyclic carbohydrate derivative) at C1 by allyl rearrangement in the presence of a catalyst is called Ferrier type-I rearrangement. 2,3-Unsaturated glycosides are usually obtained from glycals through Ferrier type-I rearrangement, and their potential biological activities have gradually attracted widespread attention of researchers. This review summarizes recent advances (2009- present) in the application of various types of catalysts to Ferrier type-I rearrangement reactions, including their synthesis, mechanism, and application of 2, 3-unsaturated glycosides.
科研通智能强力驱动
Strongly Powered by AbleSci AI