纳滤
聚酰胺
界面聚合
膜
聚合
渗透
材料科学
聚乙烯醇
化学工程
壳聚糖
高分子化学
化学
聚合物
复合材料
渗透
单体
工程类
生物化学
作者
Dong Wang,Na Zhang,Jiaojiao Zhang,Yuyao Qin,Sen Wang,Chuyang Y. Tang,Zhining Wang
出处
期刊:Desalination
[Elsevier]
日期:2023-06-01
卷期号:556: 116593-116593
被引量:7
标识
DOI:10.1016/j.desal.2023.116593
摘要
Controllable interfacial polymerization (IP) is eminently desirable for the preparation of high-performance nanofiltration (NF) membranes to address the worldwide water scarcity. Herein, we report a facile and versatile approach to prepare novel polyamide (PA) NF membranes via a hydrogel-assisted IP process. The piperazine (PIP) diffusion was precisely controlled by tailoring the viscosity of the introduced chitosan/polyvinyl alcohol (CS/PVA) hydrogel via adjusting the hydrogel composition and crosslinking degree. Due to the synergistic effect of the decreased thickness and improved surface hydrophilicity of the PA layer formed atop hydrogel, the hydrogel-regulated thin film composite (TFC-hg) membrane exhibited a high water permeance of 15.5 L m−2 h−1 bar−1, which was 2.5 times of that of the control membrane. Meanwhile, the TFC-hg membrane achieved a Na2SO4 rejection of 99.1 % due to the highly cross-linked PA separation film. This work offers a simple and highly effective strategy for constructing high-performance TFC NF membranes toward efficient water treatment.
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