离子液体
电合成
电解质
电催化剂
选择性
化学
法拉第效率
产量(工程)
无机化学
电化学
水溶液
材料科学
催化作用
电极
有机化学
物理化学
冶金
作者
Tianran Wei,Haihong Bao,Xinzhong Wang,Shusheng Zhang,Qian Liu,Jun Luo,Xijun Liu
出处
期刊:Chemcatchem
[Wiley]
日期:2023-01-04
卷期号:15 (3)
被引量:32
标识
DOI:10.1002/cctc.202201411
摘要
Abstract Ambient NH 3 electrosynthesis from NO reduction reaction (NORR) is attractive in replacing the industrial Haber‐Bosch route; however, the competitive hydrogen evolution reaction (HER) in aqueous electrolyte typically induces a limited selectivity and activity toward NH 3 production. Herein, hierarchical P‐doped MoS 2 nanospheres are developed as the NORR electrocatalyst in an ionic liquid (IL) electrolyte for catalyzing the reduction of NO to NH 3 with a maximal Faradaic efficiency of 69 % (−0.6 V vs RHE) and a peak yield rate of 388.3 μg h −1 mg cat. −1 (−0.7 V vs RHE), both of which are comparable to the best‐reported results. Moreover, the catalyst also shows stable NORR activity over 30 h and 6 cycles. Theoretical analyses further reveal that the P dopants in MoS 2 facilitate the activation and hydrogenation of NO. Besides, the employment of hydrophobic IL electrolyte also slows down the HER kinetics effectively.
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