Functional polydiynes prepared by metathesis cyclopolymerization of 1,7-dihalogen-1,6-heptadiyne derivatives

The MCP route used for the polymerization of 1,6-heptadiynes was successfully applied to the polymerization of 1,7-dihalogen-1,6-heptadiynes, and the target polymers were obtained in high yield with high molecular weight and unique UCST behavior.