Cottonseed extraction with mixtures of acetone and hexane

Abstract Cottonseed flakes were extracted with mixtures of n ‐hexane and acetone, with the concentration of acetone varying between 10 and 75%. Adding small amounts of acetone (≤25%) to n ‐hexane significantly increased the extraction of free and total gossypol from cottonseed flakes. Sensory testing detected no difference in the odor of cottonseed meals produced either by extraction with 100% n ‐hexane or by extraction with a 10∶90 (vol/vol) mixture of acetone/hexane. More than 80% of the free gossypol was removed by the 10∶90 mixture of acetone/hexane, whereas pure n ‐hexane extracted about 47% of the free gossypol from cottonseed flakes. A solvent mixture containing 25% acetone removed nearly 90% of the free gossypol that was removable by extraction with pure acetone; the residual meal had only a minimal increase in odor. In contrast, cottonseed meals produced by extraction with pure acetone had a much higher odor intensity. The composition of the cottonseed crude oil was insignificantly affected by the acetone concentration of the extraction solvent. The results indicate that mixtures of acetone and n ‐hexane can be used as extraction solvents to produce cottonseed crude oil without the concomitant development of odorous meals.