化学
配体(生物化学)
反应性(心理学)
硫醇
铜
催化作用
十二烷
共轭体系
光化学
偶联反应
高分子化学
有机化学
组合化学
医学
生物化学
替代医学
受体
病理
聚合物
作者
Irina Tarkhanova,M. G. Gantman,T. N. Rostovschikova
标识
DOI:10.1080/10426507.2011.582056
摘要
Abstract Two radical reactions (addition of CCl4 to the double bond of oct-1-ene and oxidation of dodecane-1-thiol with air oxygen) catalyzed by copper complexes have been investigated. Various nitrogen-containing compounds (aliphatic and aromatic amines, aminoalcohols, aminoacids) were used as the ligands. In both cases, products of ligand transformation have been observed, products of the transformations have been identified by GLC-MS. In case of the CCl4 addition, the reaction can be initiated by the either copper complex or the ligand. In case of the thiol coupling, the reaction proceeds as a conjugated oxidation of both the thiol and the ligand. A correlation between the donor ability of the ligand and its reactivity has been found.
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