异质结
X射线光电子能谱
光催化
材料科学
三元运算
欧姆接触
热液循环
化学工程
光电子学
纳米技术
化学
计算机科学
催化作用
工程类
生物化学
程序设计语言
图层(电子)
作者
Junxian Bai,Rongchen Shen,Weilin Chen,Jun Xie,Peng Zhang,Zhimin Jiang,Xin Li
标识
DOI:10.1016/j.cej.2021.132587
摘要
Herein, the metallic Ti3C2 nanosheets decorated 2D-2D Zn0.7Cd0.3S (ZCS)-Fe2O3 Ohmic/step-scheme (S-scheme) hybrid heterojunction with cascade 2D coupling interfaces was rationally synthesized by oil bath and hydrothermal methods. The construction of both S-scheme and Ohmic heterojunctions was identified via in-situ irradiation XPS (ISI XPS), Electron spin resonance (ESR) or ultraviolet photoelectron spectroscopy (UPS) experiments, which can greatly improve the photocatalytic H2 evolution raction (HER) rate and stability. The H2 evolution rates of ZCS/0.5 Ti3C2, ZCS/2 Fe2O3 and ZCS/0.5 Ti3C2/2 Fe2O3 were 1.91, 2.0 and 6.35 times higher than that of pure ZCS nanosheets (NSs), respectively. The optimized ternary composite exhibits a highest HER activity of 27.24 mmol g−1h−1, with an apparent quantum efficiency of 20.92% at 450 nm. Meanwhile, the ternary photocatalyst still exhibited much higher stability. Clearly, the strong S-scheme interfacial electric fields could effectively promote spatial charge separation between ZCS nanosheets and Fe2O3 nanosheets, while 2D Ti3C2 MXene nanosheets, as an Ohmic-junction H2-evolution co-catalyst, could provide more electron transfer pathways and a large number of active sites for photocatalytic HER. It is expected that this work can offer some new idea or inspirations to rationally design highly efficient S-scheme heterojunction photocatalysts for further practical applications.
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