Enhanced porous membrane fabrication using cellulose acetate and citric acid: Improved structural integrity, thermal stability, and gas permeability

In this study, our primary objective was to enhance the properties of porous membranes by addressing the limitations associated with phase separation. We employed a non-solvent induced phase separation (NIPS) method, utilizing cellulose acetate (CA) in conjunction with citric acid to fabricate these membranes. Citric acid played a dual role: ensuring a uniform pore structure and cross-linking the CA polymer, thereby enhancing its mechanical strength. This approach resulted in the development of a more robust membrane with superior structural integrity. Thermogravimetric analysis (TGA) confirmed enhanced thermal stability, particularly up to 150 °C, as a result of citric acid's cross-linking effect. Beyond 150 °C, the decomposition temperatures of the CA/citric acid membrane were found to be comparable to those of pure CA. Remarkably, a CA/citric acid ratio of 1:0.05 exhibited the slowest decomposition rate as the temperature increased. Scanning electron microscopy (SEM) examination unveiled a sponge-like membrane structure with numerous evenly distributed fine pores. Through the use of citric acid as a plasticizer, we were able to effectively control the penetration of water molecules, preventing the formation of macrovoids and promoting the creation of fine pores. This resulted in the fabrication of a high-porosity membrane, boasting an impressive porosity measurement of 84.9 %. Furthermore, measurements of the Gurley value confirmed efficient gas permeation, a critical characteristic for applications requiring effective gas transport. Fourier transform infrared (FT-IR) spectroscopy attested to the presence of citric acid in the membrane post-phase separation, indicating its successful integration. Our work presents a novel approach to enhance porous membranes, providing improvements in mechanical strength, thermal stability, and gas permeability. These findings offer valuable insights for the development of advanced materials with diverse applications in various fields.