Unlocking the Room Temperature Phosphorescence through Halogen Engineering in Carbazole Dimer

= 14.94 cm⁻¹), enabling efficient ISC and robust RTP in BrCz-D. Enhanced RTP in crystalline BrCz-D is attributed to unique halogen interactions, including Br···Br, C···Br, and H···Br, within the crystal lattice. Such halogen interactions are negligible in the solution state, accounting for the lack of RTP under ambient conditions. The present work highlights the critical role of SOC and halogen bonding in achieving efficient RTP for designing high-performance organic phosphorescent materials through crystallochemistry.