串联
化学
产量(工程)
磷酸
催化作用
组合化学
环境友好型
功能群
反应条件
级联反应
有机化学
材料科学
冶金
聚合物
复合材料
生物
生态学
作者
Lixia Quan,Xun Yi,An‐Xi Zhou,Xianhong Zhu,Liu‐Liang Mao,Jie‐Ping Wan
标识
DOI:10.1002/slct.202204778
摘要
Abstract An efficient and novel strategy for the synthesis of phosphoric esters has been developed via visible‐light‐promoted tandem oxyphosphorylation etherification of α‐diazoesters under mild conditions in the absence of any catalysts and additives. The reaction simply utilizes air (O 2 ) as the environmentally friendly and sustainable oxygen source, delivering functionalized phosphoric esters in moderate to excellent yield with operational simplicity and gram‐scale synthesis, as well as good functional‐group tolerance.
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