化学
小型商用车
Knoevenagel冷凝
串联
双功能
镧系元素
金属有机骨架
路易斯酸
吸附
热稳定性
星团(航天器)
化学稳定性
组合化学
无机化学
有机化学
催化作用
离子
复合材料
材料科学
程序设计语言
计算机科学
作者
Yue Zhang,Yuxiang Wang,Lin Liu,Na Wei,Ming‐Liang Gao,Dan Zhao,Zheng‐Bo Han
出处
期刊:Inorganic Chemistry
[American Chemical Society]
日期:2018-01-31
卷期号:57 (4): 2193-2198
被引量:153
标识
DOI:10.1021/acs.inorgchem.7b03084
摘要
A series of 12-connected lanthanide cluster based metal–organic frameworks (MOFs) have been constructed by [Ln6(μ3-OH)8(COO−)12] secondary building units (SBUs) and 2-aminobenzenedicarboxylate (BDC-NH2) ligands. These obtained materials exhibit high chemical stability and generic thermal stability, especially in acidic and basic conditions. They also present commendable CO2 adsorption capacity, and Yb-BDC-NH2 was further confirmed by a breakthrough experiment under both dry and wet conditions. Moreover, these materials possess both Lewis acid and Brønsted base sites that can catalyze one-pot tandem deacetalization–Knoevenagel condensation reactions.
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