六亚甲基四胺
加合物
化学
分子
戒指(化学)
氢键
结晶学
毒鼠强
菱形
立体化学
有机化学
几何学
数学
物理化学
作者
Ramaiyer Venkatraman,Paresh Chandra Ray,Frank R. Fronczek
标识
DOI:10.1107/s0108270104015963
摘要
Hexamethylenetetramine and rac-trans-1,2-cyclohexanedicarboxylic acid crystallize in a 1:1 ratio as a neutral molecular adduct, C6H12N4·C8H12O4. Two dicarboxylic acid molecules and two tetramine molecules form a hydrogen-bonded ring, in the shape of a rhombus, which lies on a crystallographic twofold axis bisecting the two diacid molecules. The O—H⋯N hydrogen bonds have lengths 2.6808 (19) and 2.6518 (19) Å, and, in each ring, both acid molecules have the same handedness.
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