光催化
吸附
钙钛矿(结构)
污染物
催化作用
材料科学
化学工程
水处理
环境污染
化学
无机化学
纳米技术
环境工程
环境科学
有机化学
环境保护
工程类
作者
Lei Huang,Xuanjie Huang,Jia Yan,Yonghui Liu,Hao Jiang,Hongguo Zhang,Jinfeng Tang,Qiang Liu
标识
DOI:10.1016/j.jhazmat.2022.130024
摘要
The problem of global water pollution and scarcity of water resources is becoming increasingly serious. Multifunctional perovskites can well drive adsorption and photocatalytic reactions to remove water pollutants. There are many advantages of perovskites, such as abundant oxygen vacancies, easily tunable structural morphology, stable crystal state, highly active metal sites, and a wide photo response range. However, there are few reviews on the simultaneous application of perovskite to adsorption and photocatalytic removal of water pollutants. Thus, this paper discusses the preparation methods of perovskite, the factors affecting the adsorption of water environmental pollutants by perovskite, and the factors affecting perovskite photocatalytic water pollutants. The particle size, specific surface area, oxygen vacancies, electron-hole trapping agents, potentials of the valence band, and conduction band in perovskites are significant influencing factors for adsorption and photocatalysis. Strategies for improving the performance of perovskites in the fields of adsorption and photocatalysis are discussed. The adsorption behaviors and catalytic mechanisms are also investigated, including adsorption kinetics and thermodynamics, electrostatic interaction, ion exchange, chemical bonding, and photocatalytic mechanism. It summarizes the removal of water pollutants by using perovskites. It provides the design of perovskites as high-efficiency adsorbents and catalysts for developing new technologies.
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