异构化
催化作用
金属
氘
材料科学
化学工程
光化学
无机化学
化学
冶金
有机化学
核物理学
物理
工程类
作者
Gerard V. Smith,W.E. Brower,M. S. Matyjaszczyk,Thomas L. Pettit
出处
期刊:Studies in Surface Science and Catalysis
日期:1981-01-01
卷期号:: 355-363
被引量:26
标识
DOI:10.1016/s0167-2991(09)60283-4
摘要
Pd/Si glasses, made by splat cooling, are active hydrogenation catalyst systems (catglas). During the hydrogenation with deuterium of cis-cyclododecene they produce more trans isomerization, more dideutero-saturate and less extensive exchange than crystalline Pd. Moreover, certain partially crystallized splat cooled glasses exhibit enhanced catalytic activity.
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