结晶
材料科学
热稳定性
碳纳米管
复合数
复合材料
扫描电子显微镜
等温过程
化学工程
热力学
物理
工程类
作者
Zhen Yu,Zhiguo Jiang,Zhaobin Qiu
出处
期刊:Polymer
[Elsevier]
日期:2021-08-01
卷期号:229: 124019-124019
被引量:9
标识
DOI:10.1016/j.polymer.2021.124019
摘要
The in-situ synthesis and thermal properties of biobased poly(neopentyl glycol 2,5-furandicarboxylate) (PNF)/multi-walled carbon nanotubes (MWCNTs) composites were studied in this research. The chemical structure, thermal stability, crystallization behavior, and crystal structure of PNF/MWCNTs composites were extensively investigated and compared with those of PNF. Scanning electron microscopy image revealed that MWCNTs uniformly dispersed in PNF matrix. In the composites, MWCNTs slightly improved the thermal stability of PNF, while the crystallization of PNF was obviously enhanced by MWCNTS under both the nonisothermal and isothermal crystallization conditions as the heterogeneous nucleating agent. Only 0.5 wt% of MWCNTs obviously increased the melt crystallization temperature from 132.9 °C for neat PNF to 141.2 °C for the composite and decreased the crystallization half-time from 3.1 min for neat PNF to 1.9 min for the composite at 165 °C. In addition, MWCNTs did not modify the crystal structure of PNF.
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