A bioinspired hetero-binuclear iron-molybdenum complex supported by tridentate sulfur donors and its catalytic activity toward hydrazine disproportionation

A bioinspired thiolate-bridged iron-molybdenum complex was designed and synthesized, featuring similar structural motifs as found in the {FeS3Mo} moiety of FeMoco. Spectroscopic and computational studies reveal it contains a low-spin...