薄膜复合膜
二肽
膜
反渗透
生物污染
化学工程
海水淡化
化学
结垢
嫁接
氯
聚酰胺
高分子化学
材料科学
有机化学
氨基酸
生物化学
聚合物
工程类
作者
Faiz Izzuddin Azmi,Pei Sean Goh,Ahmad Fauzi Ismail,Norhaiza Ahmad,Muhammad Nidzhom Zainol Abidin
标识
DOI:10.1016/j.reactfunctpolym.2023.105708
摘要
There has been constant progress in the development of innovative polyamide (PA) thin-film composite (TFC) reverse osmosis (RO) membranes to address limitations in fouling potential, chlorine resistance, salt rejection and water flux trade-offs. In this work, dipeptide of zwitterionic amino acid L-arginine, i.e., arginyl-arginine (Arg-Arg), was grafted on the surface of PA TFC RO membrane in order to simultaneously improve the antifouling properties, chlorine resistance, and separation performance. The interactions between the Arg-Arg dipeptide and PA layer were evidenced by Fourier transforms infrared spectroscopy and nuclear magnetic resonance spectroscopy, which have indicated the distinguished chemical grafting of Arg-Arg dipeptide on the RO membrane surface. The grafting of Arg-Arg dipeptide led to a thinner, smoother, more hydrophilic, and less negatively charged PA surface. The surface-modified membranes simultaneously exhibited enhanced desalination performances, antifouling and chlorine resistance properties. Compared to the neat TFC membrane, the water flux of Arg-Arg dipeptide-modified membrane was improved by 26.19%. The salt rejection also slightly increased from 96.25% to 98%. The roles of Arg-Arg dipeptide in altering the surface chemistry and the structure of the membranes are discussed to highlight the potential of surface-modified membranes in heightening the desalination performances of RO TFC membranes.
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