A Metal‐Organic Complex Constructed from Co(II), Azo‐amide‐pyridyl and Benzenetricarboxylate Mixed Ligands: Efficient Catalysis for Selective Oxidation of Benzyl Alcohols to Benzyl Acids

By using one-step hydrothermal synthesis, a novel metal-organic complex containing Co(II), the azo-amide-pyridyl ligand (E)-4,4'-(diazene-1,2-diyl)bis(N-(pyridin-3-yl)benzamide (DABA) and benzenetricarboxylate was synthesized, with a molecular formula of [Co₂ (DABA)_0.5 (MTC)(μ₃ -OH)(H₂ O)₂ ] ⋅ 2H₂ O (namely 1, DABA=(E)-4,4'-(diazene-1,2-diyl)bis(N-(pyridin-3-yl)benzamide, H₃ MTC=1,2,4-benzenetricarboxylic acid) which was characterized by single crystal X-ray diffraction, PXRD, IR spectroscopy, TGA, and XPS. In the structure of complex 1, tetranuclear Co(II) clusters were connected by MTC to form a 2D bilayer structure and further constructed a 3D structure with DABA ligand. Complex 1 was used as an efficient heterogeneous catalyst for the oxidation of benzyl alcohol, and the conversion rate of benzyl alcohol reached 98.6 % and the selectivity of benzoic acid reached 94.8 %. In addition, complex 1 can be reused 5 times without significant loss of activity. The oxidation of benzyl alcohol with different substituents also showed satisfactory conversion and selectivity, indicating that complex 1 had good catalytic performance.