重新使用
危险废物
光伏系统
废物管理
热的
帧(网络)
工艺工程
块(置换群论)
限制
研磨
材料科学
单晶硅
精炼(冶金)
硅
环境科学
焚化
遏制(计算机编程)
环境友好型
蒸发
导电体
玻璃回收
晶体硅
铝
背景(考古学)
生产(经济)
城市固体废物
作者
Marcelo Esposito,Almir Barbosa Reis Neto,Adelano Esposito,Oumaima Mesbahi
出处
期刊:Journal of Hazardous, Toxic, and Radioactive Waste
[American Society of Civil Engineers]
日期:2025-12-19
卷期号:30 (2)
被引量:1
标识
DOI:10.1061/jhtrbp.hzeng-1593
摘要
A bibliographical and experimental exploration of the recycling streams for monocrystalline silicon photovoltaic modules unveils ongoing limitations. Mechanical grinding processes block the efficient differentiation of conductive and insulating materials; chemical processes engender the formation of solid and liquid effluents having an adverse environmental effect; and thermal processes are limited by the production of noxious gases and by their high-energy demand, thus limiting scale-up. Hybrid processes are typically used only for recovering a given material stream. Conventional recyclers accept items like cables, connections, and junction boxes; but frames, usually separated mechanically, become contaminated by glass and sealant, losing value. Because many components of newly manufactured (after 2020) modules cannot be accepted by collecting and recycling facilities, traditional recycling processes (mechanical, thermal, and chemical) have been practically tested and proved impractical in this study: grinding hinders material separation; thermal processes emit hazardous gases and consume large amounts of energy; and chemical processes produce toxic waste without efficient delamination. To overcome these issues, we conceptualized and experimentally tested an immobile ground structure built at the landfill site only from discarded modules: the frame forms the mechanical structure and glass/laminate provides ballast, supporting and fastening new modules. Such a structure is strong, simple, and long-lasting, needing no concrete, and reduces the use of transport and landfill space. Such a reuse route overcomes the practical and economic issues we spotted in available recycling processes.
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