A new electrophilic alaninol synthon. A general route to oxazolidinones of D or (R)-2-amino alcohols from L-serine
作者
Mukund P. Sibi,Drew N. Rutherford,Rajiv Kumar Sharma
出处
期刊：Perkin Transactions [Royal Society of Chemistry] 日期：1994-01-01卷期号： (13): 1675-1675被引量：31
标识
DOI：10.1039/p19940001675
摘要
A new electrophilic alaninol synthon, (S)-4-(4′-tolylsulfonyloxymethyl)oxazolidin-2-one, derived from serine, undergoes nucleophilic displacements with Gilman cuprates and/or Grignard/CuX reagents in high yield to provide (R)-4-substituted oxazolidinones.
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吃葡萄不吐葡萄皮
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