3D Ternary Hybrid of VSe2/e‐MXene/CNT with a Promising Energy Storage Performance for High Performance Asymmetric Supercapacitor

Abstract MXene and TMDs are two of the emerging electrode materials for supercapacitors owing to their unique physicochemical properties such as high conductivity, large surface area, and rich redox active sites. However, sheet restacking, volume expansion and oxidation hinder these materials from being used in practical applications. In this work, a 3D ternary hybrid structure of metallic VSe 2 , Ti 3 C 2 T x MXene and carbon nanotube was designed to address some of the challenges in 2D materials‐based electrodes for supercapacitor application. The exfoliated MXene and CNT decorated VSe 2 3D structure showed excellent synergy between each component to deliver promising energy storage and cycling performance. The ternary hybrid structure also can suppress the surface oxidation of MXene sheets during the hydrothermal reaction. Furthermore, an asymmetric supercapacitor fabricated with VSe 2 /e‐MXene/CNT and MoS 2 /MXene delivered the highest energy density of 35.91 Wh/kg at a power density of 1280 W/kg and a remarkable cycle life.