Synthesis, Crystal Structure and Thermal Decomposition Process of Complex [Sm(BA)3phen]2

Journal of the Chinese Chemical SocietyVolume 53, Issue 2 p. 293-298 Article Synthesis, Crystal Structure and Thermal Decomposition Process of Complex [Sm(BA)3phen]2 Ning Ren, Ning Ren Experimental Center, Hebei Normal University, Shijiazhuang, 050016, P. R. China College of Chemistry & Material Science, Hebei Normal University, Shijiazhuang, 050016, P. R. ChinaSearch for more papers by this authorJian-Jun Zhang, Corresponding Author Jian-Jun Zhang jjzhang6@sohu.com Experimental Center, Hebei Normal University, Shijiazhuang, 050016, P. R. ChinaFax: +86–311–86268405Search for more papers by this authorRui-Fen Wang, Rui-Fen Wang College of Chemistry & Material Science, Hebei Normal University, Shijiazhuang, 050016, P. R. ChinaSearch for more papers by this authorShu-Ping Wang, Shu-Ping Wang College of Chemistry & Material Science, Hebei Normal University, Shijiazhuang, 050016, P. R. ChinaSearch for more papers by this author Ning Ren, Ning Ren Experimental Center, Hebei Normal University, Shijiazhuang, 050016, P. R. China College of Chemistry & Material Science, Hebei Normal University, Shijiazhuang, 050016, P. R. ChinaSearch for more papers by this authorJian-Jun Zhang, Corresponding Author Jian-Jun Zhang jjzhang6@sohu.com Experimental Center, Hebei Normal University, Shijiazhuang, 050016, P. R. ChinaFax: +86–311–86268405Search for more papers by this authorRui-Fen Wang, Rui-Fen Wang College of Chemistry & Material Science, Hebei Normal University, Shijiazhuang, 050016, P. R. ChinaSearch for more papers by this authorShu-Ping Wang, Shu-Ping Wang College of Chemistry & Material Science, Hebei Normal University, Shijiazhuang, 050016, P. R. ChinaSearch for more papers by this author First published: 25 September 2013 https://doi.org/10.1002/jccs.200600036Citations: 19AboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinked InRedditWechat Abstract A binuclear samarium(III) complex with benzoic acid and 1,10-phenanthroline, [Sm(BA)3phen]2 was synthesized and characterized by elemental analysis, UV, IR and TG-DTG techniques. The structure of the title complex was established by single crystal X-ray diffraction. The crystal is triclinic, space group P1 with a = 10.8216(11) Å, b = 11.9129(13) Å, c = 12.425(2) Å, α = 105.007(2)°, β = 93.652(2)°, γ = 113.2630(10)°, Z = 1, Dc = 1.650 mg·m−3, F(000) = 690. The carboxylate groups are bonded to the samarium ion in three modes: bidentate chelating, bidentate bridging, and tridentate chelating-bridging. Each Sm3+ ion is coordinated to one bidentate chelating carboxylate group, two bidentate bridging and two tridentate chelating-bridging carboxylate groups, as well as one 1,10-phenanthroline molecule, forming a nine-coordinate metal ion. Based on thermal analysis, the thermal decomposition process of [Sm(BA)3phen]2 has been derived. Citing Literature Volume53, Issue2April 2006Pages 293-298 RelatedInformation