级联
电化学
小学(天文学)
试剂
化学
催化作用
组合化学
过渡金属
级联反应
有机化学
电极
色谱法
物理化学
物理
天文
作者
Mingxu Wang,Ying Gao,Xiao‐Jing Zhao,Guoquan Lu,Yonghui He
摘要
An electrochemical multicomponent [2+2+1] cascade cyclization of enaminones and primary amines towards the synthesis of 4-acylimidazoles has been developed. In an undivided cell, enaminones and primary amines can smoothly participate in this reaction to provide a series of 1,2-disubstituted 4-acylimidazoles at room temperature. The reaction avoids the use of both transition-metal catalysts and oxidation reagents, which makes it more sustainable and renewable.
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