石墨
电解质
硫化物
电极
硫黄
材料科学
碳纤维
无机化学
化学工程
化学
复合材料
冶金
物理化学
复合数
工程类
作者
Sunhyung Jurng,Sangjin Park,Taeho Yoon,Hyun‐seung Kim,Hyejeong Jeong,Ji Heon Ryu,Jae Jeong Kim,Seung M. Oh
出处
期刊:Journal of The Electrochemical Society
[The Electrochemical Society]
日期:2016-01-01
卷期号:163 (8): A1798-A1804
被引量:32
摘要
This work describes the beneficial effects given by the allyl sulfide (AS)-derived surface film on the low-temperature performances of graphite electrode and the film-forming mechanism. Adding a small amount of allyl sulfide as an electrolyte additive into a Li/graphite cell increases the reversible capacity of graphite electrode to three times larger than that of the AS-free cell at −30°C. Lithium plating is also suppressed by adding AS into the background electrolyte. An impedance analysis reveals that the charge transfer resistance is significantly lower in the AS-added cell at low-temperatures. When the graphite electrode is soaked in the AS-added electrolyte, allyl sulfide is spontaneously oxidized to produce the sulfur-containing surface film. The as-generated film is then electrochemically reduced during the first lithiaiton period to produce another type of the sulfur-containing film. After repeated cycling, a carbon-rich sulfur-containing film is generated near the graphite surface, while the decomposition products of background electrolyte are deposited in the outer surface region. The presence of the carbon-rich sulfur-containing film near the graphite surface seems to be responsible for the facilitation of charge transfer reaction at low temperatures.
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