Hydrometallurgical Treatment for Valuable Metals Recovery from Spent CoMo/Al2O3 Catalyst. 2. Oxidative Leaching of an Unroasted Catalyst Using H2O2

This study deals with the feasibility of the oxidative leaching of molybdenum and cobalt sulphides contained in a spent hydrodesulphurisation catalyst using H 2 O 2 in acidic medium. The study was first carried out with MoS 2 in order to define the important parameters of the leaching procedure and then applied to an unroasted CoMo/Al 2 O 3 spent catalyst containing 11 wt % of Mo and 2.7 wt % of Co. In both cases, a 2 3 factorial design was used. The results obtained with MoS 2 highlighted the necessity to limit the increase in temperature of the medium to minimize the decomposition of H 2 O 2 and the necessity to keep pH constant to avoid an important acidification of the medium which could cause dissolution of alumina matrix when leaching will be applied to spent catalysts. The oxidative leaching of the unroasted CoMo/Al 2 O 3 spent catalyst was performed without previous grinding. In a single-step, at pH = 1.3 with a stoichiometric factor equal to 2.4, an L / S ratio equal to 7.5, and an H 2 O 2 concentration of 3.75 mol·L −1, it was possible to recover molybdenum and cobalt simultaneously with leaching yields of 90% and 83%, respectively, without dissolving more than 8% Al. In these conditions, the maximal temperature recorded during the experiment was about 60 °C.