Flame retardant and smoke-suppressant rigid polyurethane foam based on sodium alginate and aluminum diethylphosphite

In order to improve the flame-retardant effect and thermal behaviour of rigid polyurethane foam (RPUF), the flame retardancy of sodium alginate (SA), aluminium diethyl phosphite (ADPO₂) and expandable graphite (EG) were proposed. First, the structures of RPUF with or without flame retardancy were confirmed by scanning electron microscopy (SEM). Additionally, the combustion behaviours and thermal performance of the flame-retardant polyurethane were evaluated through thermogravimetric analysis (TGA), limiting oxygen index (LOI) tests, and UL-94 tests. Finally, the cone calorimeter results reveled the RPUF/5ADPO₂/7.5SA/7.5EG exhibit excellent thermodynamic properties. The results of the heat release rate (HRR), total heat release (THR), total smoke production (TSP), and smoke production rate (SPR) could demonstrate the smoke-suppressant and flame-retardant of polyurethane. The system of RPUF/ADPO₂/SA/EG showed excellent flame-retardant in polyurethane.