阳极
石墨
锂(药物)
插层(化学)
材料科学
离子
电池(电)
电压
电极
化学
电气工程
复合材料
工程类
热力学
物理
无机化学
功率(物理)
物理化学
有机化学
内分泌学
医学
作者
Min‐Soo Kim,Inwoo Kim,J. Kim,Jang Wook Choi
出处
期刊:ACS energy letters
[American Chemical Society]
日期:2023-06-09
卷期号:8 (7): 2946-2953
被引量:9
标识
DOI:10.1021/acsenergylett.3c00695
摘要
Lithium ion batteries for electric vehicles demand high-level monitoring of their safety and long-term cyclability. To this end, identifying defective cells at the postmanufacturing stage would be the most effective approach. Here, we introduce the lithiation heterogeneity as a key descriptor for inspecting and grading as-manufactured cylindrical cells. Specifically, the peak intensity of the differential voltage (DV) profile during charge provides a quantitative indication of the heterogeneity of lithium ion intercalation into graphite, in relation to the staging effect of the graphite anode. The degree of heterogeneity determined by the DV profile is closely correlated with the cycle life, implying that the heterogeneity analysis can serve as a useful tool for inspecting as-manufactured cells and predicting their cycle life at an early stage. Moreover, the ability to accurately grade as-manufactured cells allows a high-performance battery module to be built by integrating cells with low heterogeneity and minor deviations in their performance.
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