Preparation of cellulose gel extracted from rice straw and its application for metal ion removal from aqueous solutions

纤维素 吸附 水溶液 弗伦德利希方程 吸附剂 化学 生物吸附 水溶液中的金属离子 核化学 稻草 材料科学 金属 吸附 无机化学 有机化学
作者
Manal M. El-Zawahry,Ahmed Hassabo,Amina L. Mohamed
出处
期刊:International Journal of Biological Macromolecules [Elsevier BV]
卷期号:248: 125940-125940 被引量:11
标识
DOI:10.1016/j.ijbiomac.2023.125940
摘要

Rice straw waste was used to extract natural cellulose fibers, which was then chemically converted to cellulose gel. Both extracted cellulose and modified cellulose (gel) were characterized using different techniques and used for biosorption of b+arium, manganese, cobalt, nickel, copper, zinc, and cadmium. Both celluloses' chemical compositions were investigated. The FT-IR, XRD, TEM, and SEM results all support the success of the proposed chemical modification. Because of the increase in pore size within the gel composition, the metal sorption capability of the final chelating material (gel) was greater than that of extracted cellulose. The experimental data were fit to the sorption isotherm models of Langmuir, Freundlich, and Temkin. This new modified biopolymer's behaviour suggested that it could be used as a promising sorbent for cation removal from polluted dye baths and waste water. Furthermore, this modified cellulose was prepared as cheap material extracted from the rise waste which helping in protection of the environment and it was confirm excellent behaviour in the removal heavy metals from their aqueous solution compared to the previous materials reported before.
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