化学
钪
谱线
相(物质)
相变
化学物理
物理化学
无机化学
凝聚态物理
有机化学
天文
物理
作者
S. Turrell,S. Hafsi,P. Conflant,P. Barbier,M. Drache,J.C. Champarnaud-Mesjard
标识
DOI:10.1016/0022-2860(88)80199-6
摘要
Abstract The combined Raman, crystallographic and thermal data confirm the existence of two tetragonal and one cubic phase for the M 3 ScF 6 (MRb, Cs, Tl) compounds. Normal-coordinate calculations suggest that the tetragonal→tetragonal rearrangement results from a decrease in the cation-F interaction, thus yielding two octahedra with more similar environments. The tetragonal→cubic transition results in a crystal with all Sc-F bonds equivalent.
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