光电子学
有机发光二极管
光致发光
电致发光
三苯胺
佩多:嘘
二极管
量子产额
作者
Peili Gao,Jianing Wang,Lunhui Wang,Dan Wang,Wen Peng,Shuhua Zou,Yueqi Mo,Yong Zhang
标识
DOI:10.1016/j.orgel.2021.106138
摘要
Abstract Highly efficient and stable blue quantum-dot light-emitting diodes (QD-LEDs) have been realized by using poly (9,9-bis(N-(2′-ethylhexyl)-carbazole-3-yl)-2,7-fluorene) (PFCz) as hole-transporting layers (HTLs). Due to the carbazole units as substituents at the 9-position of polyfluorene, PFCz shows higher hole mobility and better electrochemical stability than poly (N-vinlycarbazole) (PVK). As a result, the maximum current efficiency (CE) and external quantum efficiency (EQE) of the blue QD-LEDs increased from 4.32 cd A−1 to 7.9% for PVK HTL to 7.38 cd A−1 and 12.61% for PFCz HTL, respectively. Furthermore, the PFCz-based blue QD-LED exhibited lower turn-on voltage and longer device lifetime than the PVK-based device. The improvement performance of blue QD-LED should be attributed to the conjugated fluorene backbone and the substituents of the carbazole active sites, thus enhancing hole mobility and electrochemical stability. This result demonstrates that polyfluorenes with pendent carbazole groups is a promising hole-transporting materials for improving performance of blue QD-LEDs.
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