阴极
材料科学
电化学
水溶液
经济短缺
热液循环
化学工程
纳米技术
电池(电)
电极
电气工程
化学
工程类
物理化学
政府(语言学)
功率(物理)
哲学
物理
量子力学
语言学
作者
Yang-Yi Liu,Tingting Lv,Hai Wang,Xiaolei Guo,Chun‐Sen Liu,Huan Pang
标识
DOI:10.1016/j.cej.2021.128408
摘要
Aqueous Zn-ion batteries (ZIBs) have gained considerable interest because of cost-effectiveness, high safety, and high theoretical capacities. However, the shortage of high-performance cathode materials hinders their practical application on large scale. In this study, nsutite-type VO2 microcrystals that were prepared via a hydrothermal method and applied as cathode materials in ZIBs is reported. The nsutite-type VO2 microcrystal cathodes exhibited high specific capacity (314.4 mAh g−1 at 1 A g−1), excellent energy densities, and an ultrahigh capacity retention of 84% after 5000 cycles at 5 A g−1. Furthermore, by combining with various in-situ and ex-situ measurements, we found that VO2 nanotables that were formed in the electrochemical process contributed to enhancing the electrochemical performance. We believe that the facile synthetic method and excellent performances of the nsutite-type VO2 microcrystal cathodes can pave the way for the future improvements in the synthetic methodology of cathode materials in ZIBs.
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