选择性
掺杂剂
煅烧
材料科学
化学工程
兴奋剂
多孔性
带隙
花粉
比表面积
催化作用
纳米技术
有机化学
化学
复合材料
光电子学
工程类
生态学
生物
作者
Xia Jiang,Yang Liu,Haijiao Hao,Yan Xu,Jiale Huang,Daohua Sun,Qingbiao Li
出处
期刊:ACS Sustainable Chemistry & Engineering
[American Chemical Society]
日期:2017-12-15
卷期号:6 (1): 882-888
被引量:37
标识
DOI:10.1021/acssuschemeng.7b03228
摘要
Herein, we described a mild and facile method for the synthesis of three-dimensional (3D) hierarchically porous TiO2. This method simultaneously realized the C,N self-dopant, introduced more surface defectives, and decreased in the band-gap energy (Eg) of TiO2. Rape pollen was chosen as the biotemplate to prepare TiO2, and the pore property of the obtained products could be adjusted by changing the amount of Ti precursor and calcination temperature. The as-synthesized pollen-TiO2 not only duplicated the morphology of rape pollen, but also showed enhanced 1-butene selectivity in the reaction of selective hydrogenation of 1,3-butadiene after loading elemental Pd, when comparing with the commercial TiO2. Butenes selectivity of 98% and 1-butene selectivity of 66% were achieved at 50 °C, because of the hierarchically porous structure of pollen-TiO2 and the lower Eg and more surface defects resulting from the C,N dopant.
科研通智能强力驱动
Strongly Powered by AbleSci AI