Stable cycling of high-voltage lithium metal batteries in ether electrolytes

The key to enabling long-term cycling stability of high-voltage lithium (Li) metal batteries is the development of functional electrolytes that are stable against both Li anodes and high-voltage (above 4 V versus Li/Li+) cathodes. Due to their limited oxidative stability (  90% over 300 cycles and ~80% over 500 cycles with a charge cut-off voltage of 4.3 V. This study offers a promising approach to enable ether-based electrolytes for high-voltage Li metal battery applications. Ether-based electrolytes offer many advantages compared to other electrolyte systems, but they are not stable in Li metal batteries when operating at high voltages. Here, the authors develop a concentrated ether electrolyte that enables long-term cycling stability of high-voltage Li metal batteries.