钙钛矿(结构)
光伏系统
材料科学
能量转换效率
太阳能电池
三苯胺
混合太阳能电池
电子迁移率
半导体
光电子学
硅
晶体硅
纳米技术
工程物理
聚合物太阳能电池
电气工程
化学
结晶学
物理
工程类
作者
Zhihao Song,Shirong Wang,Yin Xiao,Xianggao Li
出处
期刊:Chinese Physics
[Acta Physica Sinica, Chinese Physical Society and Institute of Physics, Chinese Academy of Sciences]
日期:2015-01-01
卷期号:64 (3): 033301-033301
被引量:5
标识
DOI:10.7498/aps.64.033301
摘要
Perovskite solar cells with a solid-state thin film structure have attracted great attention in recent years due to their simple structure, low production cost and superb photovoltaic performance. Because of the boost in power conversion efficiency (PCE) in short intervals from 3.8% to 19.3% at present, this hybrid cells have been considered as the next generation photovoltaic devices. It is expected that the efficiencies of individual devices could ultimately achieve 25%, which is comparable to the single-crystal silicon solar cell.In this article, the perovskite absorber, its basic device structure, and operating principles are briefly introduced. Since most of the high efficiency perovskite solar cells employ hole transporting materials (HTM), they could benefit the hole transport and improve the metal-semiconductor interface in the cells. This perspective gives analyses of some effective hole transporting materials for perovskite solar cell application. The hole transporting materials used in perovskite solar cell are classified into six categories according to their structures, including triphenylamine-based small molecule HTM, small molecule HTM containing N atom, sulfur-based small molecule HTM, sulfur-based polymer HTM, polymer HTM containing N atom and inorganic HTM. Emphasis is placed on the interplay of molecular structures, energy levels, and charge carrier mobility as well as device parameters. A critial look at various approaches applied to achieve desired materials and device performance is provided to assist in the identification of new directions and further advances.
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