硼
乙二胺
荧光粉
光致发光
无机化学
溶剂热合成
溶剂
兴奋剂
胺气处理
沸石
材料科学
白光
化学
有机化学
催化作用
光电子学
作者
Mingsheng Wang,Guo‐Cong Guo,Wen‐Tong Chen,Gang Xu,Wen Zhou,Kejun Wu,Jin‐Shun Huang
标识
DOI:10.1002/anie.200604946
摘要
Intrinsic white borate phosphors: Solvothermal reaction of H3BO3 and ethylenediamine afforded the first three-dimensional zeolite-like ammonium borate. Its blue photoluminescence can be modified to white by a simple heat-treatment process at 250, at 360, or at 250 °C after doping with Eu3+ ions (see picture, left to right). In the absence of solvent, the same solvothermal reaction gave the first amine-pillared layer borate-based framework.
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