Solar‐Powered Interfacial Evaporation and Deicing Based on a 3D‐Printed Multiscale Hierarchical Design

Abstract Solar‐powered interfacial heating has emerged as a sustainable technology for hybrid applications with minimal carbon footprints. Aerogels, hydrogels, and sponges/foams are the main building blocks for state‐of‐the‐art photothermal materials. However, these conventional three‐dimensional (3D) structures and related fabrication technologies intrinsically fail to maximize important performance‐enhancing strategies and this technology still faces several performance roadblocks. Herein, monolithic, self‐standing, and durable aerogel matrices are developed based on composite photothermal inks and ink‐extrusion 3D printing, delivering all‐in‐one interfacial steam generators (SGs). Rapid prototyping of multiscale hierarchical structures synergistically reduce the energy demand for evaporation, expand actual evaporation areas, generate massive environmental energy input, and improve mass flows. Under 1 sun, high water evaporation rates of 3.74 kg m−2 h−1 in calm air and 25.3 kg m−2 h−1 at a gentle breeze of 2 m s−1 are achieved, ranking among the best‐performing solar‐powered interfacial SGs. 3D‐printed microchannels and hydrophobic modification deliver an icephobic surface of the aerogels, leading to self‐propelled and rapid removal of ice droplets. This work shines light on rational fabrication of hierarchical photothermal materials, not merely breaking through the constraints of solar‐powered interfacial evaporation and clean water production, but also discovering new functions for photothermal interfacial deicing.