高分辨率透射电子显微镜
材料科学
锑
氧化锡
纳米颗粒
掺杂剂
锡
化学工程
氯化物
兴奋剂
纳米技术
氧化锑
透射电子显微镜
无机化学
氧化物
冶金
化学
光电子学
工程类
作者
J. Liu,James P. Coleman,P. Madhukar
标识
DOI:10.1017/s1431927600009053
摘要
Antimony-doped tin oxide (ATO) materials have many interesting and useful properties for industrial applications. Important uses of ATO include anti-static pigments, catalysts, electrochromic devices, solar cells, gas sensors, etc. Although the electro-optical and the structural properties of ATO materials with low dopant levels have been extensively investigated,the fundamental structural/chemical properties of heavily doped ATO materials have not been well understood. We report here some preliminary results of a systematic study of the structural evolution of tin oxide nanopaiticles heavily doped with antimony. The ATO powders were prepared by adding a mixture of antimony(V) chloride and tin(IV) chloride to deionised water with concurrent addition of sodium hydroxide. The resulting white precipitates were filtered, washed and dried at room temperature. A series of Sb-doped SnO 2 samples was obtained by annealing the precipitates at various temperatures. Samples suitable for high resolution transmission electron microscopy (HRTEM) were prepared by dry-dispersing ATO powders onto holey carbon films.
科研通智能强力驱动
Strongly Powered by AbleSci AI