硝基
化学
区域选择性
酰胺
催化作用
产量(工程)
腈
选择性
配体(生物化学)
选择性还原
组合化学
溶剂
有机化学
药物化学
材料科学
冶金
受体
烷基
生物化学
作者
Upendra Sharma,Praveen Kumar Verma,Neeraj Kumar,Vishal Kumar,Manju Bala,Bikram Singh
标识
DOI:10.1002/chem.201003621
摘要
Abstract Iron phthalocyanine with iron sulfate has been successfully applied for high chemo‐ and regioselective reduction of aromatic nitro compounds to give the corresponding amines in a green solvent system without using any toxic ligand. The catalytic systems were also compatible with a large range of other reducible functional groups, such as keto, acid, amide, ester, halogen, lactone, nitrile, N ‐benzyl, O ‐benzyl, hydroxy, and heterocycles. In the present study, dinitro compounds have been regioselectively reduced to the corresponding amines with high yield. In most of the cases the conversion and selectivity was greater than 99 % as determined by GC‐MS analysis.
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