The experimental study of concentration and recovery of sodium sulfate(Na 2SO 4) from its solution was done with electrodialysis process. The results indicated that Na 2SO 4 can be removed and concentrated very well by this method. The maximum concentration of Na 2SO 4 can reach as high as 14%. It costs about 450-1150kWh for the recovery of 1t Na 2SO 4. Therefore, we can see that electrodialysis is an idea and convenient way of concentration and recovery of Na 2SO 4.