咪唑酯
催化作用
双功能
纳米颗粒
煅烧
甲醇
纳米复合材料
沸石咪唑盐骨架
脱质子化
无机化学
材料科学
化学工程
锌
化学
吸附
纳米技术
物理化学
有机化学
金属有机骨架
离子
工程类
作者
Yuxiang Mao,Jun Cheng,Hao Guo,Lei Qian,Jiacan Tu,Weijuan Yang
标识
DOI:10.1016/j.apsusc.2023.158047
摘要
A bifunctional ZnO/Zn-NC catalyst coupling ZnO nanoparticles and Zn single atoms anchored on N-doped carbon nanocomposite was synthesized through breaking saturated Zn-N4 structures of zeolitic imidazolate frameworks (ZIF-8) to facilitate microalgal lipids conversion. DFT calculations showed that ZnO nanoparticles and Zn (single atoms)-N2 sites in ZA-400 catalyst, which was derived from calcination of ZIF-8 at 400 °C, reduced energy barrier of esterification by 0.50 eV and 0.38 eV compared with Zn-N4 site, respectively. Methanol reactant exhibited stronger activation and deprotonation ability on pyridinic nitrogen and lattice oxygen. The ZA-400 catalyst with an increased Lewis acidity (3.209 mmol/g) and basicity (0.592 mmol/g) exhibited a high conversion efficiency of 98.1% in microalgal biodiesel production.
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