High adsorption capacity of ammonia nitrogen on hexagonal porous aluminosilicate derived from solid-waste bagasse bottom ash

This study investigates the use of a hexagonal-porous aluminosilicate (HAS) adsorbent derived from bagasse bottom ash (BBA), an agricultural solid waste, for the adsorption of ammonia nitrogen (NH3-N)-a key water pollutant from agricultural and farming activities. Sodium silicate derived from BBA via the alkaline fusion method was employed, resulting in energy savings due to a synthesis temperature 1.53 times lower than that of commercial sodium silicate synthesis. The sol-gel method was utilized to successfully synthesize HAS featuring a high surface area and porosity using the sodium silicate prepared from BBA. However, an increase in aluminum content resulted in a decrease in surface area and hexagonal porosity. In performance tests, the HAS(5) adsorbent exhibited the most efficient NH3-N removal, outperforming other adsorbents by 4.54-25.19 times across all initial concentrations. This enhanced efficiency can be attributed to its numerous acidic surface sites, enabling the bonding of NH3-N molecules through monolayer adsorption on the HAS surface.