超级电容器
纳米片
材料科学
电容
电解质
电极
球体
化学工程
层状双氢氧化物
功率密度
纳米技术
化学
氢氧化物
功率(物理)
量子力学
天文
物理
工程类
物理化学
作者
Xu Zhang,Lu Wang,Yuhan Tian,Shixuan Yang,Qiang Zhang,Da Lei,Yingyuan Zhao
标识
DOI:10.1016/j.jcis.2021.08.094
摘要
Layered double hydroxides (LDHs) have been considered as favorable pseudocapacitive electrode materials for supercapacitors due to their tunable layered structure/compositions and low cost. Here, we report the NiCo-LDH hollow spheres prepared with Co-glycerate as the sacrificial template and cobalt source. The hollow spheres are assembled with frizzy NiCo-LDH nanosheets, where the hollow structure can inhibit agglomeration of the LDH nanosheets to expose more active sites and shorten the diffusion path of electrolyte ions. The prepared NiCo-LDH hollow spheres show a high specific capacitance of 1962 F g-1 at 1 A g-1 and good capacitance retention rate of 66.4 % at 30 A g-1. The asymmetric supercapacitors fabricated using NiCo-LDH hollow spheres as positive electrode yields a large energy density 62.9 Wh kg-1 at the power density of 0.8 kW kg-1. This research may develop a facile synthesis way to prepare LDH hollow spheres for supercapacitors.
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