Supplementary cementing materials in concrete

For comparing the relative performance of various supplementary cementing materials (SCMs: silica fume, fly ash, slag, natural pozzolans, etc.) as regards Portland cement, the practical concept of an efficiency factor may be applied. The efficiency factor (or k value) is defined as the part of the SCM in an SCM-concrete that can be considered as equivalent to Portland cement. In the present work, an alternative procedure for experimental determination of the k value is proposed, using the concept of the pozzolanic activity index. For the first time, also, the k value for equivalent strength was correlated with the active silica content of the SCM through analytical expressions. Artificial pozzolanic materials of various compositions and some natural pozzolans were studied. It was found and verified by experimental comparison that these expressions are valid only for artificial SCMs (fly ash, slag), whereas in the case of natural SCMs the k value is overestimated. Thus, knowing primarily the active silica content of the SCM, a first approximation of the k value can be obtained and, further, the strength of a concrete incorporating artificial SCM can be predicted.