降级(电信)
复合数
氢氧化物
化学
阿特拉津
吸附
污染物
光催化
西维因
无机化学
核化学
环境化学
材料科学
催化作用
杀虫剂
有机化学
复合材料
生物
电信
计算机科学
农学
作者
Ji Shu,Kanming Wang,Virender K. Sharma,Xiping Xu,Nasri Nesnas,Hongyu Wang
标识
DOI:10.1016/j.cej.2022.141127
摘要
This paper presents Fe(VI) combined with Ti/Zn layered double hydroxide (Fe(VI)-Ti/Zn LDH) as a composite to degrade organic pollutants (pesticides and pharmaceuticals) under visible light (VL). The Fe(VI)-LDH/VL system was shown to effectively activate Fe(VI) and simultaneously enhance separation and migration of electrons-holes on the Ti/Zn LDH surface. Furthermore, the Fe(III) particles resulting from the Fe(VI) reduction were adsorbed and coordinated onto the LDH surface to form an in-situ heterojunction photocatalyst which narrowed the wide bandgap from 3.08 eV to 1.44 eV of the LDH and achieved further oxidation of pollutants. Detailed kinetic and mechanistic investigations using the pesticide, imidacloprid (IMI), revealed multi-oxidant intermediate species (FeV/FeIV, OH, hVB+ and O2−) involved in degrading the parent micropollutant and yielding oxidized products. This study also assessed the application of Fe(VI)-Ti/Zn LDH composite to other pesticides and pharmaceuticals (carbaryl (CAB) and metribuzin (MBZ), trimethoprim (TMP) and carbamazepine (CBZ)), and exhibited satisfactory micropollutants removal. The newly reported VL-induced Fe(VI) activation system, based on Fe(VI)-Ti/Zn LDH composite, may be an effective multi-oxidant strategy to oxidize pollutants in water.
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