甲酸脱氢酶
甲酸
化学
电化学
格式化
无机化学
核化学
酶
辅因子
电极
有机化学
催化作用
物理化学
作者
Yijing Chen,Peng Li,Hyunho Noh,Chung Wei Kung,Cassandra T. Buru,Xingjie Wang,Xuan Zhang,Omar K. Farha
标识
DOI:10.1002/anie.201901981
摘要
Abstract The efficient fixation of excess CO 2 from the atmosphere to yield value‐added chemicals remains crucial in response to the increasing levels of carbon emission. Coupling enzymatic reactions with electrochemical regeneration of cofactors is a promising technique for fixing CO 2 , while producing biomass which can be further transformed into biofuels. Herein, a bioelectrocatalytic system was established by depositing crystallites of a mesoporous metal–organic framework (MOF), termed NU‐1006, containing formate dehydrogenase, on a fluorine‐doped tin oxide glass electrode modified with Cp*Rh(2,2′‐bipyridyl‐5,5′‐dicarboxylic acid)Cl 2 complex. This system converts CO 2 into formic acid at a rate of 79±3.4 m m h −1 with electrochemical regeneration of the nicotinamide adenine dinucleotide cofactor. The MOF–enzyme composite exhibited significantly higher catalyst stability when subjected to non‐native conditions compared to the free enzyme, doubling the formic acid yield.
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