吡啶
热重分析
高分子化学
四氟硼酸盐
差示扫描量热法
玻璃化转变
材料科学
甲苯
聚合物
聚合
芳烯
盐(化学)
离子液体
化学
有机化学
烷基
催化作用
物理
热力学
芳基
作者
Frank W. Harris,Kathy C. Chuang,Shel Ann X. Huang,James J. Janimak,Stephen Z. D. Cheng
出处
期刊:Polymer
[Elsevier]
日期:1994-11-01
卷期号:35 (23): 4940-4948
被引量:50
标识
DOI:10.1016/0032-3861(94)90648-3
摘要
A series of phenylated, aromatic poly(pyridinium tetrafluoroborate)s has been prepared by the polymerization of 4,4′-(1,4-phenylene)bis(2,6-diphenylpyrylium tetrafluoroborate) with aromatic diamines in a dimethylsulfoxide/toluene mixture at 145–150°C. The water generated by the transformation of the pyrylium rings to pyridinium rings was distilled from the reaction mixture as a water/toluene azeotrope. All-para-catenated, rigid-rod polymers with inherent viscosities as high as 4.9 dl g−1 were obtained that were soluble in polar aprotic solvents. The polymers could be solution cast into tough, flexible films. Although the glass transition temperatures of the poly(pyridinium salt)s were difficult to detect with differential scanning calorimetry, they displayed distinctive melting endotherms with minima above 380°C. Thermogravimetric analysis showed that the polymers began to decompose near 360°C prior to melting. Wide-angle X-ray diffraction analysis revealed that the chains were packed in a structure similar to that of a smectic liquid crystalline glass.
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