光催化
煅烧
钛酸锶
溶胶凝胶
结晶度
材料科学
马弗炉
差热分析
化学工程
钛酸酯
透射电子显微镜
无机化学
矿物学
催化作用
核化学
陶瓷
化学
纳米技术
冶金
薄膜
复合材料
衍射
有机化学
工程类
物理
光学
作者
Liang Chen,Shouchen Zhang,Liqiu Wang,Dongfeng Xue,Shu Yin
标识
DOI:10.1016/j.jcrysgro.2008.09.185
摘要
Abstract On the basis of our previous work, we developed a new type of catalyst (e.g. photocatalysts) to degradate nitrogen oxides (NO x ). Recently, a series of photocatalysts such as strontium titanate (SrTiO 3 ) were prepared by sol–gel method, their photocatalytic activities of NO degradation were also studied. The obtained samples were characterized by differential thermal analysis and thermal gravimetric analysis, X-ray diffraction and transmission electron microscopy. The as-prepared photocatalysts have a perfect perovskite structure, and pure samples can be obtained when the corresponding sol–gel precursors were calcined at 600 °C in muffle. With the temperature increasing, the grain size of SrTiO 3 samples grew large steadily and the crystallinity became better. The optimal synthesis of SrTiO 3 was determined to be 700 °C calcination. Our current experiments indicated that some parameters such as lamp-house, calcinations temperature had a strong effect on the designed photoreaction, the concentration of nitric oxide at 716 mg/m 3 , the degradation rate of nitric oxide can increase above 92%.
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