Highly efficient mesoporous polymer supported phosphine-gold( i ) complex catalysts for amination of allylic alcohols and intramolecular cyclization reactions

PAuCl (3d) was identified as the most efficient catalyst. Compared to the homogeneous catalyst, the enhanced catalytic activity of the heterogeneous gold(i) catalyst is closely related to the mesoporous structure of FDU-15. The catalytic system was suitable for a broad range of substrates and can be easily recovered and recycled at least twelve times without significant loss of catalytic activity. In addition, the catalytic performance of 3d was further examined for intramolecular cyclization for the synthesis of heterocyclic compounds.